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What is the difference between Polyaluminium Chloride and Aluminium Chlorohydrate
In the water treatment industry, Polyaluminium Chloride (PAC) and Aluminium Chlorohydrate (ACH) are two commonly used high-efficiency coagulants that are often compared. While they share similarities in appearance and application scope, they differ significantly in chemical structure, flocculation mechanisms, treatment efficiency, and cost-effectiveness.
For procurement managers of large-scale water treatment projects, understanding the differences between PAC and ACH is essential, as it directly affects treatment performance, cost control, and regulatory compliance. This article provides a comprehensive comparison of these two coagulants—covering chemical properties, treatment performance, application scenarios, and procurement considerations—to help buyers make informed and rational decisions.
Let’s dive into a detailed comparison and uncover the strengths and limitations of PAC and ACH in modern water treatment.
Polyaluminium Chloride (PAC)
Polyaluminium Chloride (PAC) is an inorganic polymer coagulant produced by hydrolysis and polymerization of aluminum salts under controlled conditions. It is a highly efficient coagulant that works by forming positively charged polymeric aluminum ions through hydrolysis, which neutralize charges, destabilize suspended solids, and promote the formation of flocs.
Aluminium Chlorohydrate (ACH)
Aluminium Chlorohydrate (ACH) is a high-concentration, pre-hydrolyzed aluminum coagulant typically found in colorless to light yellow liquid or powder form. It consists mainly of highly polymerized hydroxy-aluminum ions and is known for its very high basicity and excellent charge neutralization.
Advantages of ACH:
High basicity—requires minimal pH adjustment, reducing pH correction costs.
Strong adaptability—performs better in low-temperature, low-turbidity conditions, ideal for winter or challenging scenarios.
Lower residual aluminum—produces water with less aluminum residue, essential for drinking water safety.
Stable liquid formula—has a longer shelf life than PAC solutions.
High purity—suitable for sensitive industries like pharmaceuticals, cosmetics, food, and beverage.
Chemical and Performance Differences
Feature
Polyaluminium Chloride (PAC)
Aluminium Chlorohydrate (ACH)
Basicity
40–70%
≥80%
Al₂O₃ Content
10–18% liquid / ~30% powder
23–24%
Form
Powder, granule, liquid
Primarily liquid
pH Range
5–9
5–9 (better in cold water)
Sludge Production
Moderate
Lower sludge volume
Residual Aluminum
Low
Very low
Stability
Powder very stable, liquid less so
Liquid highly stable
Cost
Lower, widely used
Higher, premium-grade
Main Uses
Municipal & industrial, wastewater
Drinking water, pharma, cosmetics, ultrapure water
FAQ
What’s the difference between ACH and PAC?
PAC and ACH are both efficient aluminum-based coagulants. ACH is a high-concentration, high-basicity variant of PAC with higher Al13 content and stronger charge neutralization. It requires lower dosage and leaves less residual aluminum. PAC is more cost-effective and versatile, widely used in municipal and industrial wastewater, while ACH’s higher basicity and lower residuals make it ideal for drinking water and premium applications.
Which is better for drinking water: PAC or ACH?
ACH is usually better for drinking water due to its lower residual aluminum and minimal pH impact at low dosages. PAC is also suitable, especially for large-scale municipal systems where cost-effectiveness is critical.
Does ACH reduce residual aluminum better than PAC?
Yes. ACH’s high basicity and polymerization allow for more efficient aluminum ion removal during treatment, significantly lowering residual aluminum levels in treated water. It is the preferred choice for high-standard potable water treatment.
Conclusion
Polyaluminium Chloride (PAC) and Aluminium Chlorohydrate (ACH) are two vital aluminum-based coagulants, each with distinct advantages in the water treatment industry. Choosing between them depends on specific treatment goals. PAC remains the top choice for large-scale, cost-sensitive projects due to its affordability and wide applicability. ACH offers superior efficiency, lower residuals, and higher stability—making it the ideal solution for drinking water and specialized high-end industries.
For buyers, the decision should consider water quality, performance targets, cost control, compliance requirements, and supply chain reliability. A well-informed selection between PAC and ACH ensures effective treatment, economic feasibility, and sustainable operations.
OYI provides customized PAC and related water treatment chemicals (PAM, SDIC, TCCA) to global industrial clients. Backed by a 3,000 m² factory, ample inventory, and fast delivery, we help you achieve safe, compliant, and cost-effective water treatment solutions.
Contact: oyi@oyipolymer.com
Request samples, technical datasheets, and bulk procurement support.